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Going around the Kok cycle of the water oxidation reaction with femtosecond X-ray crystallography.
Bhowmick A, Simon PS, Bogacz I, Hussein R, Zhang M, Makita H, Ibrahim M, Chatterjee R, Doyle MD, Cheah MH, Chernev P, Fuller FD, Fransson T, Alonso-Mori R, Brewster AS, Sauter NK, Bergmann U, Dobbek H, Zouni A, Messinger J, Kern J, Yachandra VK, Yano J. Bhowmick A, et al. Among authors: dobbek h. IUCrJ. 2023 Nov 1;10(Pt 6):642-655. doi: 10.1107/S2052252523008928. IUCrJ. 2023. PMID: 37870936 Free PMC article.
Catalysis at a dinuclear [CuSMo(==O)OH] cluster in a CO dehydrogenase resolved at 1.1-A resolution.
Dobbek H, Gremer L, Kiefersauer R, Huber R, Meyer O. Dobbek H, et al. Proc Natl Acad Sci U S A. 2002 Dec 10;99(25):15971-6. doi: 10.1073/pnas.212640899. Proc Natl Acad Sci U S A. 2002. PMID: 12475995 Free PMC article.
The cluster is coordinated through interactions of the Mo with the dithiolate pyran ring of molybdopterin cytosine dinucleotide and of the Cu with the Sgamma of Cys-388, which is part of the active-site loop VAYRC(388)SFR. The previously reported active-site structure [Dobbek
The cluster is coordinated through interactions of the Mo with the dithiolate pyran ring of molybdopterin cytosine dinucleotide and of the C …
O2 Inhibition of Ni-Containing CO Dehydrogenase Is Partly Reversible.
Merrouch M, Hadj-Saïd J, Domnik L, Dobbek H, Léger C, Dementin S, Fourmond V. Merrouch M, et al. Among authors: dobbek h. Chemistry. 2015 Dec 21;21(52):18934-8. doi: 10.1002/chem.201502835. Epub 2015 Nov 16. Chemistry. 2015. PMID: 26568460
106 results