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Is the Electrophilicity of the Metal Nitrene the Sole Predictor of Metal-Mediated Nitrene Transfer to Olefins? Secondary Contributing Factors as Revealed by a Library of High-Spin Co(II) Reagents.
Kalra A, Bagchi V, Paraskevopoulou P, Das P, Ai L, Sanakis Y, Raptopoulos G, Mohapatra S, Choudhury A, Sun Z, Cundari TR, Stavropoulos P. Kalra A, et al. Among authors: cundari tr. Organometallics. 2021 Jun 4;40(12):1974-1996. doi: 10.1021/acs.organomet.1c00267. Organometallics. 2021. PMID: 35095166 Free PMC article.
A versatile tripodal Cu(I) reagent for C-N bond construction via nitrene-transfer chemistry: catalytic perspectives and mechanistic insights on C-H aminations/amidinations and olefin aziridinations.
Bagchi V, Paraskevopoulou P, Das P, Chi L, Wang Q, Choudhury A, Mathieson JS, Cronin L, Pardue DB, Cundari TR, Mitrikas G, Sanakis Y, Stavropoulos P. Bagchi V, et al. Among authors: cundari tr. J Am Chem Soc. 2014 Aug 13;136(32):11362-81. doi: 10.1021/ja503869j. Epub 2014 Aug 5. J Am Chem Soc. 2014. PMID: 25025754
Nitrene transfer from a sterically confined copper nitrenoid dipyrrin complex.
Carsch KM, North SC, DiMucci IM, Iliescu A, Vojáčková P, Khazanov T, Zheng SL, Cundari TR, Lancaster KM, Betley TA. Carsch KM, et al. Among authors: cundari tr. Chem Sci. 2023 Sep 26;14(39):10847-10860. doi: 10.1039/d3sc03641c. eCollection 2023 Oct 11. Chem Sci. 2023. PMID: 37829016 Free PMC article.
203 results