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Threshold photodetachment spectroscopy of the astrochemical anion CN.
Simpson M, Nötzold M, Schmidt-May A, Michaelsen T, Bastian B, Meyer J, Wild R, Gianturco FA, Milovanović M, Kokoouline V, Wester R. Simpson M, et al. Among authors: michaelsen t. J Chem Phys. 2020 Nov 14;153(18):184309. doi: 10.1063/5.0029841. J Chem Phys. 2020. PMID: 33187436
Imaging dynamic fingerprints of competing E2 and SN2 reactions.
Carrascosa E, Meyer J, Zhang J, Stei M, Michaelsen T, Hase WL, Yang L, Wester R. Carrascosa E, et al. Among authors: michaelsen t. Nat Commun. 2017 Jun 21;8(1):25. doi: 10.1038/s41467-017-00065-x. Nat Commun. 2017. PMID: 28638140 Free PMC article.
Unexpected Indirect Dynamics in Base-Induced Elimination.
Meyer J, Carrascosa E, Michaelsen T, Bastian B, Li A, Guo H, Wester R. Meyer J, et al. Among authors: michaelsen t. J Am Chem Soc. 2019 Dec 26;141(51):20300-20308. doi: 10.1021/jacs.9b10575. Epub 2019 Dec 12. J Am Chem Soc. 2019. PMID: 31782654
The observed mechanistic fingerprints are associated with the E2 reaction, because steric hindrance at the alpha-carbon suppresses the S(N)2 reaction [Carrascosa, E.; Meyer, J.; Zhang, J.; Stei, M.; Michaelsen, T.; Hase, W. L.; Yang, L.; Wester, R. Nat. Commun. 2017 …
The observed mechanistic fingerprints are associated with the E2 reaction, because steric hindrance at the alpha-carbon suppresses the S(N)2 …
Imaging Reaction Dynamics of F-(H2O) and Cl-(H2O) with CH3I.
Bastian B, Michaelsen T, Li L, Ončák M, Meyer J, Zhang DH, Wester R. Bastian B, et al. Among authors: michaelsen t. J Phys Chem A. 2020 Mar 12;124(10):1929-1939. doi: 10.1021/acs.jpca.0c00098. Epub 2020 Feb 26. J Phys Chem A. 2020. PMID: 32050071 Free PMC article.
285 results