Influence of halogen bonding on gold(i)-ligand bond components and DFT characterization of a gold-iodine halogen bond.
Buttarazzi E , Rosi F , Ciancaleoni G .
Buttarazzi E , et al. Among authors: ciancaleoni g.
Phys Chem Chem Phys. 2019 Sep 18;21(36):20478-20485. doi: 10.1039/c9cp03811f.
Phys Chem Chem Phys. 2019.
PMID: 31463502
Indeed, in the presence of iodoperfluoroalkanes as XB donors, iodine interacts with the lone pair of the coordinated selenium, enhancing the Au C sigma donation and depressing the Au C pi back-donation, as demonstrated also by the increase of the rotational barrier of the C-N bon …
Indeed, in the presence of iodoperfluoroalkanes as XB donors, iodine interacts with the lone pair of the coordinated selenium, enhancing the …