Mechanistic Variants in Gas-Phase Metal-Oxide Mediated Activation of Methane at Ambient Conditions.
Li J, Zhou S, Zhang J, Schlangen M, Usharani D, Shaik S, Schwarz H.
Li J, et al. Among authors: zhang j.
J Am Chem Soc. 2016 Sep 7;138(35):11368-77. doi: 10.1021/jacs.6b07246. Epub 2016 Aug 23.
J Am Chem Soc. 2016.
PMID: 27518766
This is in distinct contrast to the [XYO2](+) (X, Y = Mg, Al, Si) cluster oxide ions which activate methane exclusively via the PCET route (Li, J.; Zhou, S.; Zhang, J.; Schlangen, M.; Weiske, T.; Usharani, D.; Shaik, S.; Schwarz, H. J. Am. Chem. Soc. 2 …
This is in distinct contrast to the [XYO2](+) (X, Y = Mg, Al, Si) cluster oxide ions which activate methane exclusively via the PCET route ( …