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Diquinol Functionality Boosts the Superoxide Dismutase Mimicry of a Zn(II) Complex with a Redox-Active Ligand while Maintaining Catalyst Stability and Enhanced Activity in Phosphate Solution.
Moore JL, Oppelt J, Senft L, Franke A, Scheitler A, Dukes MW, Alix HB, Saunders AC, Karbalaei S, Schwartz DD, Ivanović-Burmazović I, Goldsmith CR. Moore JL, et al. Among authors: schwartz dd. Inorg Chem. 2022 Dec 12;61(49):19983-19997. doi: 10.1021/acs.inorgchem.2c03256. Epub 2022 Nov 29. Inorg Chem. 2022. PMID: 36445832
A macrocyclic quinol-containing ligand enables high catalase activity even with a redox-inactive metal at the expense of the ability to mimic superoxide dismutase.
Karbalaei S, Franke A, Oppelt J, Aziz T, Jordan A, Pokkuluri PR, Schwartz DD, Ivanović-Burmazović I, Goldsmith CR. Karbalaei S, et al. Among authors: schwartz dd. Chem Sci. 2023 Sep 5;14(36):9910-9922. doi: 10.1039/d3sc02398b. eCollection 2023 Sep 20. Chem Sci. 2023. PMID: 37736643 Free PMC article.
71 results