Crystal structure and optical properties of the [Ag62S12(SBu(t))32](2+) nanocluster with a complete face-centered cubic kernel.
Jin S, Wang S, Song Y, Zhou M, Zhong J, Zhang J, Xia A, Pei Y, Chen M, Li P, Zhu M.
Jin S, et al. Among authors: wang s.
J Am Chem Soc. 2014 Nov 5;136(44):15559-65. doi: 10.1021/ja506773d. Epub 2014 Oct 24.
J Am Chem Soc. 2014.
PMID: 25343538
The crystal structure of the [Ag62S12(SBu(t))32](2+) nanocluster (denoted as NC-I) has been successfully determined, and it shows a complete face-centered-cubic (FCC) Ag14 core structure with a Ag48(SBu(t))32 shell configuration interconnected by 12 sulfide ions, which is similar …
The crystal structure of the [Ag62S12(SBu(t))32](2+) nanocluster (denoted as NC-I) has been successfully determined, and it shows a complete …