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Synthesis of a uranium(VI)-carbene: reductive formation of uranyl(V)-methanides, oxidative preparation of a [R2C═U═O]2+ analogue of the [O═U═O]2+ uranyl ion (R = Ph2PNSiMe3), and comparison of the nature of U(IV)═C, U(V)═C, and U(VI)═C double bonds.
Mills DP, Cooper OJ, Tuna F, McInnes EJ, Davies ES, McMaster J, Moro F, Lewis W, Blake AJ, Liddle ST. Mills DP, et al. J Am Chem Soc. 2012 Jun 20;134(24):10047-54. doi: 10.1021/ja301333f. Epub 2012 Jun 7. J Am Chem Soc. 2012. PMID: 22621395
White phosphorus activation by a Th(III) complex.
Formanuik A, Ortu F, Beekmeyer R, Kerridge A, Adams RW, Mills DP. Formanuik A, et al. Among authors: mills dp. Dalton Trans. 2016 Feb 14;45(6):2390-3. doi: 10.1039/c5dt04528b. Epub 2016 Jan 13. Dalton Trans. 2016. PMID: 26758474 Free article.
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