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Simple access to β-trifluoromethyl-substituted ketones via copper-catalyzed ring-opening trifluoromethylation of substituted cyclopropanols.
Chem Commun (Camb). 2015 May 14;51(39):8349-52. doi: 10.1039/c5cc02386f.
Chem Commun (Camb). 2015.
PMID: 25882978
Synthesis of γ-keto sulfones by copper-catalyzed oxidative sulfonylation of tertiary cyclopropanols.
Konik YA, Elek GZ, Kaabel S, Järving I, Lopp M, Kananovich DG.
Konik YA, et al.
Org Biomol Chem. 2017 Oct 11;15(39):8334-8340. doi: 10.1039/c7ob01605k.
Org Biomol Chem. 2017.
PMID: 28936517
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Two-step conversion of carboxylic esters into distally fluorinated ketones via ring cleavage of cyclopropanol intermediates: application of sulfinate salts as fluoroalkylating reagents.
Konik YA, Kudrjashova M, Konrad N, Kaabel S, Järving I, Lopp M, Kananovich DG.
Konik YA, et al.
Org Biomol Chem. 2017 May 31;15(21):4635-4643. doi: 10.1039/c7ob00680b.
Org Biomol Chem. 2017.
PMID: 28513753
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