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Symmetric halogen bonding is preferred in solution.
Carlsson AC, Gräfenstein J, Budnjo A, Laurila JL, Bergquist J, Karim A, Kleinmaier R, Brath U, Erdélyi M. Carlsson AC, et al. Among authors: kleinmaier r. J Am Chem Soc. 2012 Mar 28;134(12):5706-15. doi: 10.1021/ja301341h. Epub 2012 Mar 16. J Am Chem Soc. 2012. PMID: 22384818
Substituent Effects on the [N-I-N](+) Halogen Bond.
Carlsson AC, Mehmeti K, Uhrbom M, Karim A, Bedin M, Puttreddy R, Kleinmaier R, Neverov AA, Nekoueishahraki B, Gräfenstein J, Rissanen K, Erdélyi M. Carlsson AC, et al. Among authors: kleinmaier r. J Am Chem Soc. 2016 Aug 10;138(31):9853-63. doi: 10.1021/jacs.6b03842. Epub 2016 Jun 17. J Am Chem Soc. 2016. PMID: 27265247 Free PMC article.
Solvent effects on 15N NMR coordination shifts.
Kleinmaier R, Arenz S, Karim A, Carlsson AC, Erdélyi M. Kleinmaier R, et al. Magn Reson Chem. 2013 Jan;51(1):46-53. doi: 10.1002/mrc.3907. Epub 2012 Dec 4. Magn Reson Chem. 2013. PMID: 23208996