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Gas-phase kinetics of chlorosilylene reactions II. ClSiH + C2H4: absolute rate measurements and quantum chemical and RRKM calculations for the prototype pi addition reaction.
Chemphyschem. 2010 Feb 1;11(2):419-28. doi: 10.1002/cphc.200900490.
Chemphyschem. 2010.
PMID: 19998305
A comparison of the reactivity of germylene and dimethylgermylene with some methylgermanes. Direct kinetic and quantum chemical studies.
Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R.
Becerra R, et al. Among authors: promyslov vm.
Phys Chem Chem Phys. 2007 Aug 21;9(31):4395-406. doi: 10.1039/b706148j. Epub 2007 Jun 29.
Phys Chem Chem Phys. 2007.
PMID: 17687486
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Surprisingly slow reaction of dimethylsilylene with dimethylgermane: time-resolved kinetic studies and related quantum chemical calculations.
Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R.
Becerra R, et al. Among authors: promyslov vm.
J Phys Chem A. 2008 Feb 7;112(5):849-57. doi: 10.1021/jp710740a. Epub 2008 Jan 15.
J Phys Chem A. 2008.
PMID: 18193853
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Gas-phase kinetics of chlorosilylene reactions. I. ClSiH + Me3SiH: absolute rate measurements and theoretical calculations for prototype Si-H insertion reactions.
Becerra R, Boganov SE, Egorov MP, Faustov VI, Krylova IV, Nefedov OM, Promyslov VM, Walsh R.
Becerra R, et al. Among authors: promyslov vm.
J Phys Chem A. 2009 May 14;113(19):5512-8. doi: 10.1021/jp901446t.
J Phys Chem A. 2009.
PMID: 19382797
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Unusual isotope effect in the reaction of chlorosilylene with trimethylsilane-1-d. Absolute rate studies and quantum chemical and Rice-Ramsperger-Kassel-Marcus calculations provide strong evidence for the involvement of an intermediate complex.
Becerra R, Boganov SE, Egorov MP, Krylova IV, Promyslov VM, Walsh R.
Becerra R, et al. Among authors: promyslov vm.
J Am Chem Soc. 2012 Jun 27;134(25):10493-501. doi: 10.1021/ja301924b. Epub 2012 Jun 14.
J Am Chem Soc. 2012.
PMID: 22632068
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A highly delocalized triplet carbene, 5-Methylhexa-1,2,4-triene-1,3-diyl: matrix IR identification, structure, and reactions.
Boganov SE, Faustov VI, Shavrin KN, Gvozdev VD, Promyslov VM, Egorov MP, Nefedov OM.
Boganov SE, et al. Among authors: promyslov vm.
J Am Chem Soc. 2009 Oct 21;131(41):14688-98. doi: 10.1021/ja901508c.
J Am Chem Soc. 2009.
PMID: 19775132
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