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Iron-mediated intramolecular metalative cyclization of alpha,beta-unsaturated esters and amides. Versatile one-pot preparation of bicyclic ketoesters.
Org Lett. 2008 Nov 6;10(21):5031-3. doi: 10.1021/ol802170z. Epub 2008 Oct 15.
Org Lett. 2008.
PMID: 18855398
Iron-catalyst-switched selective conjugate addition of grignard reagents: alpha,beta,gamma,delta-unsaturated amides as versatile templates for asymmetric three-component coupling processes.
Okada S, Arayama K, Murayama R, Ishizuka T, Hara K, Hirone N, Hata T, Urabe H.
Okada S, et al. Among authors: hirone n.
Angew Chem Int Ed Engl. 2008;47(36):6860-4. doi: 10.1002/anie.200801928.
Angew Chem Int Ed Engl. 2008.
PMID: 18666190
No abstract available.
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Iron-mediated and -catalyzed metalative cyclization of electron-withdrawing-group-substituted alkynes and alkenes with Grignard reagents.
Hata T, Sujaku S, Hirone N, Nakano K, Imoto J, Imade H, Urabe H.
Hata T, et al. Among authors: hirone n.
Chemistry. 2011 Dec 16;17(51):14593-602. doi: 10.1002/chem.201101273. Epub 2011 Nov 23.
Chemistry. 2011.
PMID: 22114030
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Acceleration of the substitution of silanes with Grignard reagents by using either LiCl or YCl3/MeLi.
Hirone N, Sanjiki H, Tanaka R, Hata T, Urabe H.
Hirone N, et al.
Angew Chem Int Ed Engl. 2010 Oct 11;49(42):7762-4. doi: 10.1002/anie.201003174.
Angew Chem Int Ed Engl. 2010.
PMID: 20821779
No abstract available.
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