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The complete characterization of a rhodium Lewis acid-dipolarophile complex as an intermediate for the enantioselective catalytic 1,3-dipolar cycloaddition of C,N-diphenylnitrone to methacrolein.
Carmona D, Lamata MP, Viguri F, Rodríguez R, Oro LA, Balana AI, Lahoz FJ, Tejero T, Merino P, Franco S, Montesa I. Carmona D, et al. Among authors: lamata mp. J Am Chem Soc. 2004 Mar 10;126(9):2716-7. doi: 10.1021/ja031995z. J Am Chem Soc. 2004. PMID: 14995185
Enantioselective 1,3-dipolar cycloaddition of nitrones to methacrolein catalyzed by (eta5-C5Me5)M{(R)-prophos} containing complexes (M = Rh, Ir; (R)-prophos = 1,2-bis(diphenylphosphino)propane): on the origin of the enantioselectivity.
Carmona D, Lamata MP, Viguri F, Rodríguez R, Oro LA, Lahoz FJ, Balana AI, Tejero T, Merino P. Carmona D, et al. Among authors: lamata mp. J Am Chem Soc. 2005 Sep 28;127(38):13386-98. doi: 10.1021/ja0539443. J Am Chem Soc. 2005. PMID: 16173773