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Escherichia coli chorismate synthase catalyzes the conversion of (6S)-6-fluoro-5-enolpyruvylshikimate-3-phosphate to 6-fluorochorismate. Implications for the enzyme mechanism and the antimicrobial action of (6S)-6-fluoroshikimate.
Bornemann S, Ramjee MK, Balasubramanian S, Abell C, Coggins JR, Lowe DJ, Thorneley RN. Bornemann S, et al. Among authors: abell c. J Biol Chem. 1995 Sep 29;270(39):22811-5. doi: 10.1074/jbc.270.39.22811. J Biol Chem. 1995. PMID: 7559411 Free article.
The substrate analogue (6S)-6-fluoro-5-enolpyruvylshikimate-3-phosphate is a competitive inhibitor of Neurospora crassa chorismate synthase (Balasubramanian, S., Davies, G. M., Coggins, J. R., and Abell, C. (1991) J. Am. Chem. Soc. 113, 8945-8946). We have shown tha …
The substrate analogue (6S)-6-fluoro-5-enolpyruvylshikimate-3-phosphate is a competitive inhibitor of Neurospora crassa chorismate synthase …
Observation of a secondary tritium isotope effect in the chorismate synthase reaction.
Balasubramanian S, Coggins JR, Abell C. Balasubramanian S, et al. Among authors: abell c. Biochemistry. 1995 Jan 10;34(1):341-8. doi: 10.1021/bi00001a042. Biochemistry. 1995. PMID: 7819217
Previous experiments have measured a primary deuterium isotope effect on V/K at C(6) [Balasubramanian, S., Abell, C., & Coggins, J. R. (1990) J. ...In the light of these observations the reaction mechanism probably involves cleavage of the C(6)-H a …
Previous experiments have measured a primary deuterium isotope effect on V/K at C(6) [Balasubramanian, S., Abell, C., & …
401 results