Asymmetric enone epoxidation by short solid-phase bound peptides: further evidence for catalyst helicity and catalytic activity of individual peptide strands.
Berkessel A, Koch B, Toniolo C, Rainaldi M, Broxterman QB, Kaptein B.
Berkessel A, et al.
Biopolymers. 2006;84(1):90-6. doi: 10.1002/bip.20413.
Biopolymers. 2006.
PMID: 16283656
In the presence of short solid-phase bound peptide catalysts, the Julia-Colonna epoxidation of enones (such as chalcone) with hydrogen peroxide can be performed with high enantiomeric excess (> or = 95% ee). It was proposed earlier (A. Berkessel, N. Gasch, K. Gla …
In the presence of short solid-phase bound peptide catalysts, the Julia-Colonna epoxidation of enones (such as chalcone) with hydrogen perox …