Spatially resolved transport properties in radially compressed bead packings studied by PFG NMR

Magn Reson Imaging. 1998 Jun-Jul;16(5-6):703-6. doi: 10.1016/s0730-725x(98)00018-6.

Abstract

Pulsed field gradient (PFG) multi-echo (ME) and turbo spin-echo (TSE) imaging is used to study dispersive flow in radially compressed chromatographic columns packed with porous silica beads. By using the pulsed field gradient turbo spin-echo sequence spatially resolved displacement imaging can be accelerated by a factor of 16. The positive effect of homogeneous radial packing on flow velocity and dispersion is demonstrated. Small heterogeneities of only a few percent are shown to cause changes of the dispersion coefficient of up to 50%.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Chromatography*
  • Diffusion
  • Echo-Planar Imaging
  • Humans
  • Magnetic Resonance Spectroscopy*
  • Particle Size
  • Porosity
  • Silicon Dioxide*

Substances

  • Silicon Dioxide