Bis(acetylacetonato-O,O')(eta 4-trans-2,4-hexadiene)ruthenium(II) 1/6-ethanol solvate

E Meléndez; R Ilarraza; G P Yap; A L Rheingold

doi:10.1107/s0108270197016958

Bis(acetylacetonato-O,O')(eta 4-trans-2,4-hexadiene)ruthenium(II) 1/6-ethanol solvate

Acta Crystallogr C. 1998 Apr 15:54 ( Pt 4):449-51. doi: 10.1107/s0108270197016958.

Authors

E Meléndez¹, R Ilarraza, G P Yap, A L Rheingold

Affiliation

¹ Department of Chemistry, University of Puerto Rico, Mayaquez 00681, USA.

PMID: 9604306
DOI: 10.1107/s0108270197016958

Abstract

The title compound, [Ru(C5H7O2)2(C6H10)].1/6C2H6O, has a pseudo-octahedrally coordinated RuII center, where two coordination sites are occupied by a diene ligand. The diene ligand exhibits a eta 4-trans-diene coordination mode. The compound crystallizes in space group R3, incorporating disordered ethanol in cylindrical voids.

Publication types

Research Support, U.S. Gov't, P.H.S.

MeSH terms

Crystallography, X-Ray
Ligands
Models, Molecular
Molecular Structure
Organometallic Compounds / chemistry*
Ruthenium*

Substances

Ligands
Organometallic Compounds
bis(acetylacetonato-O,O')(2,4-hexadiene)ruthenium(II)
Ruthenium