Tritium behavior in soil and mineral rock components used for plant cultivation

Appl Radiat Isot. 2024 May 8:210:111344. doi: 10.1016/j.apradiso.2024.111344. Online ahead of print.

Abstract

Immersion, percolation and tritium release experiments in peat and vermiculite soil samples were performed to analyze their behavior in this widely used medium for plant cultivation. Samples were immersed in tritiated water for 696 h and the isotope exchange capacity evaluated. A vertical flow regime was also considered with analysis for hydraulic conductivity to understand tritium mobility and therefore its availability. Peat soil showed a high tritium retention after percolation, but vermiculite seem to suppress its retention ability. The high moisture and organic content of peat enhanced its isotope exchange capacity. The falling head method was used to numerically evaluate the saturated hydraulic conductivity and outflow flux. Calculated isotope exchange capacity was 4.95×10-2 mol-T2O/g for peat and 3.38×10-2 mol-T2O/g for vermiculite. The tritium release experiment showed significant release of tritiated carbons in peat.

Keywords: Immersion; Isotope exchange capacity; Soil; Tritium percolation; Tritium release.