Electroactive materials are central to myriad applications, including energy storage, sensing, and catalysis. Compared to traditional inorganic electrode materials, redox-active organic materials such as porous organic polymers (POPs) and covalent organic frameworks (COFs) are emerging as promising alternatives due to their structural tunability, flexibility, sustainability, and compatibility with a range of electrolytes. Herein, we discuss the challenges and opportunities available for the use of redox-active organic materials in organoelectrochemistry, an emerging area in fine chemical synthesis. In particular, we highlight the utility of organic electrode materials in photoredox catalysis, electrochemical energy storage, and electrocatalysis and point to new directions needed to unlock their potential utility for organic synthesis. This Perspective aims to bring together the organic, electrochemistry, and polymer communities to design new heterogeneous electrocatalysts for the sustainable synthesis of complex molecules.
© 2024 The Authors. Published by American Chemical Society.