Characterization of Interfacial Corrosion Behavior of Hybrid Laminate EN AW-6082 ∪ CFRP

Materials (Basel). 2024 Apr 19;17(8):1907. doi: 10.3390/ma17081907.

Abstract

The corrosion behavior of a hybrid laminate consisting of laser-structured aluminum EN AW-6082 ∪ carbon fiber-reinforced polymer was investigated. Specimens were corroded in aqueous NaCl electrolyte (0.1 mol/L) over a period of up to 31 days and characterized continuously by means of scanning electron and light microscopy, supplemented by energy dispersive X-ray spectroscopy. Comparative linear sweep voltammetry was employed on the first and seventh day of the corrosion experiment. The influence of different laser morphologies and production process parameters on corrosion behavior was compared. The corrosion reaction mainly arises from the aluminum component and shows distinct differences in long-term corrosion morphology between pure EN AW-6082 and the hybrid laminate. Compared to short-term investigations, a strong influence of galvanic corrosion on the interface is assumed. No distinct influences of different laser structuring and process parameters on the corrosion behavior were detected. Weight measurements suggest a continuous loss of mass attributed to the detachment of corrosion products.

Keywords: CFRP; EN AW-6082; corrosion exposure; galvanic corrosion; hybrid laminate; intrinsic bonding; laser structuring; linear sweep voltammetry; materials engineering; surface modification.