Influence of Double-Pulse Electrodeposition Parameters on the Performance of Ag/AgCl Electrochemical Electrode for Marine Electric Field

Sensors (Basel). 2024 Mar 25;24(7):2103. doi: 10.3390/s24072103.

Abstract

This paper describes a Ag/AgCl electrochemical electrode for marine electric field measurements, which was prepared by depositing silver chloride on a silver foil substrate using double-pulse electrodeposition. The impact of positive direction peak current density and deposition time on electrode performance in the preparation of Ag/AgCl electrodes through double-pulse electrodeposition was investigated. Scanning electron microscopy and voltammetry have been used to study the properties of the prepared electrodes. This work reveals the correlation between the electrochemical behavior of electrodes and the physical properties of their surfaces, especially specific surface area and porosity. The study verified the characteristics of Ag/AgCl marine electric field electrodes obtained with different pulse parameters by analyzing the potential stability and noise level of the electrode in salt water. The study's results have positive significance for improving the accuracy of marine electric field measurements.

Keywords: Ag/AgCl marine electric field electrode; deposition time; double-pulse electrodeposition method; positive direction peak current density.