Effective detection of the concentration of Ag+ ions in bactericidal fluid is one of the necessary conditions for their effective utilization for sterilization. A novel 2D Cd(II) coordination polymer (CP1), named as [Cd(HDPN)(4,4'-bbpy)]·2H2O, was hydrothermally synthesized using 5-(2',4'-dicarboxylphenyl) nicotic acid (H3DPN) and 4,4'-bis(imidazolyl)biphenyl (4,4'-bbpy). The structure analysis discovered that CP1 possessed a 2D network structure of dinuclear inorganic building blocks. Fluorescence sensing discovered that CP1 could high-sensitively detect Ag+, tetracycline, nitrobenzene and pyrimethanil and the lowest limit of detection (LOD) were 1.44 × 10-8M, 2.15 × 10-8M, 8.09 × 10-8M, and 2.54 × 10-7M, respectively. It is worth noting that the quenching occurs after the addition of Ag+ to the aqueous solution of CP1, and then it gradually recovers when one of the halide anions (X- = Cl-, Br- and I-) is added, forming a unique "on-off-on" fluorescence sensor for Ag+ and constructing a simple logic gate. The fluorescence sensing mechanism of CP1 was investigated using ultraviolet-visible spectroscopy, PXRD, XPS, and DFT methods. The research indicates that CP1 is anticipated to serve as an excellent multifunctional fluorescence sensor, especially as a switch-type sensor for Ag+ and the halide anions.
Keywords: 2D Cd(II) network; Crystal structure; Fluorescence sensing; Fluorescence switch; Sensing mechanism.
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