Modification of wood lignin and integration with multifunctional polyester nanocomposite

Abstract

A simple strategy was introduced to develop fluorescent wood with the ability to alter its color when exposed to both visible and ultraviolet lights. Injecting a combination of europium and dysprosium doped aluminate (EDA; 7-12 nm) nanoparticles and polyester resin (PET) into a lignin-modified wood (LMW) produced a translucent smart wooden window with fluorescence and afterglow emission properties. In order to prevent formation of aggregates and improve the preparation process of transparent woods, EDA must be properly disseminated in the polyester matrix. We analyzed the fluorescent wood samples using a variety of spectroscopic and microscopic methods, including energy-dispersive X-ray (EDX), scanning electron microscopy (SEM), photoluminescence spectra, and hardness tests. We found that the photoluminescent woods had an excitation peak at 365 nm and emission peaks at 437 nm and 517 nm. The translucent luminous woods showed rapid and reversible emission response to ultraviolet light. Fluorescence emission was detected for samples with lower EDA content, and afterglow emission was detected for wood samples with higher EDA content. Increases in EDA content were associated with improvements in water resistance and ultraviolet radiation protection in the EDA@PET-infiltrated wood.

Keywords: Modification of wood lignin; Optical wood; Polyester resin.