Enhanced hydrogen uptake of dihydrogen complex via porous materials support

RSC Adv. 2024 Apr 9;14(16):11452-11455. doi: 10.1039/d4ra01182a. eCollection 2024 Apr 3.

Abstract

This research focuses on enhancing H2 adsorption by using the [Mo(PCy3)2(CO)3] complex supported on porous materials such as silica gel and mesoporous carbon. The study reports a significant increase in hydrogen adsorption capacity, reaching up to 9.3 times that of the bulk complex. This improvement suggests that using mesoporous materials as supports for the [Mo(PCy3)2(CO)3] complex enhances the accessibility of H2 gas to its open-metal sites.