Maximizing oil recovery: Innovative chemical EOR solutions for residual oil mobilization in Kazakhstan's waterflooded sandstone oilfield

Heliyon. 2024 Mar 28;10(7):e28915. doi: 10.1016/j.heliyon.2024.e28915. eCollection 2024 Apr 15.

Abstract

The results of an experimental study to design a chemical flood scheme for a massive Kazakhstani oilfield with high water cut are presented in this paper. A meticulously formulated chemical flooding procedure entails injecting a blend comprising interfacial tension (IFT) reducing agents, alkaline/nanoparticles to control chemical adsorption, and polymer to facilitate mobility control. Overall, this well-conceived approach leads to a significant enhancement in the mobilization and production of residual oil. Experiments were conducted in Kazakhstan's Field A, one of the country's oldest oilfields with over 90% water cut and substantial remaining oil, to assess the efficiency of various hydrolyzed polyacrylamide (HPAM) derived polymers and surfactant solutions. Additionally, the effectiveness of alkaline and nanoparticles in minimizing chemical adsorption for the screened surfactant and polymer was investigated. These assessments were conducted under reservoir conditions, with a temperature of 63 °C, and using 13,000 ppm Caspian seawater as makeup brine. The performance assessment of the selected chemicals was carried out through a set of oil displacement tests on reservoir cores. Critical parameters, including chemical adsorption, interfacial tension, resistance factor, and oil recovery factor, were compared to determine the most effective chemical flooding approach for Field A. Both the surfactant-polymer (SP) and alkali-surfactant-polymer (ASP) approaches were more successful in recovering residual oil by efficiently generating and delivering microemulsion, producing more than 90% of the remaining oil after waterflooding. Due to the low increase in recovery compared to SP and the complexity of applying ASP at the field scale, SP was recommended for the pilot test studies. This investigation underscores that the choice of chemicals is contingent upon the interplay between the specific characteristics of the oil, the geological formation, the injection water, and the reservoir rock. Consequently, assessing all potential configurations on reservoir cores is imperative to identify the most optimal chemical combination. The practical challenges at the field scale should also be considered for the final decision. The results of this study contribute to the successful design and implementation of tailored chemical flooding to challenging oilfields with excessive water cut and high residual oil.