Cellulose nanofiber-based multifunctional composite films integrated with zinc doped-grapefruit peel-based carbon quantum dots

Int J Biol Macromol. 2024 May;267(Pt 1):131397. doi: 10.1016/j.ijbiomac.2024.131397. Epub 2024 Apr 4.

Abstract

This study aimed to develop a multifunctional active composite film to extend the shelf life of minced pork. The composite film was prepared by incorporating zinc-doped grapefruit peel-derived carbon quantum dots (Zn-GFP-CD) into a cellulose nanofiber (CNF) matrix. The resulting film significantly improved UV-blocking properties from 39.0 % to 85.7 % while maintaining the film transparency. Additionally, the CNF/Zn-GFP-CD5% composite film exhibits strong antioxidant activity with ABTS and DPPH radical scavenging activities of 99.8 % and 77.4 %, respectively. The composite film also showed excellent antibacterial activity against both Gram-negative and Gram-positive bacteria. When used in minced pork packaging, the composite films effectively inhibit bacterial growth, maintaining bacterial levels below 7 Log CFU/g after 15 days and sustaining a red color over a 21-day storage period. Additionally, a significant reduction in the lipid oxidation of the minced pork was observed. These CNF/Zn-GFP-CD composite films have a great potential for active food packaging applications to extend shelf life and maintain the visual quality of packaged meat.

Keywords: Active packaging; Carbon quantum dots; Cellulose nanofiber; Grapefruit peel; Minced pork.

MeSH terms

  • Animals
  • Anti-Bacterial Agents / chemistry
  • Anti-Bacterial Agents / pharmacology
  • Antioxidants / chemistry
  • Antioxidants / pharmacology
  • Carbon* / chemistry
  • Cellulose* / chemistry
  • Citrus paradisi* / chemistry
  • Food Packaging* / methods
  • Nanofibers* / chemistry
  • Quantum Dots* / chemistry
  • Swine
  • Zinc* / chemistry

Substances

  • Cellulose
  • Zinc
  • Carbon
  • Antioxidants
  • Anti-Bacterial Agents