Flow electrode capacitive desalination of industrial RO reject

Abstract

Flow electrode capacitive deionization (FCDI) is a promising technology for efficiently treating industrial brine with high salt content. However, its desalination performance is currently limited by internal resistance. Achieving an effective FCDI system relies on active electrode materials with high conductivity. This study compares the desalination performances of the widely used flow electrode activated carbon (AC) with more conductive materials, reduced graphene oxide (rGO), and ZnO/rGO composite. Additionally, the lack of particle-to-particle contact in the flow electrode contributes to internal resistance and to address this, a cationic surface-active agent is introduced. This agent forms a stable dispersion, creating a space for enhanced mass loading of the active material. This modification enhances the conductive network and particle contact, reducing the diffusion path and promoting rapid ion transport. With a 5 wt% loading, ZnO/rGO achieved a 73% salt removal efficiency, surpassing AC at 63%. Furthermore, the surfactant-modified ZnO/rGO flow electrode with a 7 wt% loading demonstrated an 81% salt removal efficiency.

Keywords: Desalination; Flow electrode capacitive deionization; Industrial RO reject; Industrial brine; Metal oxide-graphene composite; Surfactant modified flow electrode.