High energy capability in poly(vinylidene fluoride-co-chlorotrifluoroethylene) nanocomposite incorporated with Ag@polyaniline@covalent organic framework core-shell nanowire

Abstract

The development of polymer film with large electrical displacement is essential for the applications of lightweight and compact energy storage. The dielectric diversity at interface of polymer composite should be addressed to realize the film capacitor with high energy density and dielectric reliability. In this work, poly(vinylidene fluoride-co-chlorotrifluoroethylene) (P(VDF-CTFE)) nanocomposite was incorporated by core-shell nanowire with covalent organic framework (COF) outer coating to alleviate the dielectric mismatch at interface. After the preparation of Ag nanowire through polyol reduction, polyaniline (PANI) and COF layers were sequentially deposited to construct core-shell Ag@polyaniline@covalent organic framework (Ag@PANI@COF) nanowire. According to the unique core-shell architecture, the COF framework is utilized to suppress the remanent polarization while high electrical displacement is preserved by the center Ag nanowire. The maximum energy density of 25.0 J/cm³ at 425 MV/m is obtained in 0.1 wt% stretched Ag@PANI@COF/P(VDF-CTFE) nanocomposite. The presence of core-shell nanowire depresses the distribution distortion of electric field and the diffusion of charge carriers under high field. This work demonstrates an effective method to develop the polymer film with large electrical displacement, and sheds a light on insightful exploration of interfacial polarized mechanism in polymer dielectric composite.

Keywords: Composite film; Covalent organic framework; Dielectric property; Interfacial polarization; Nanowire.