A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds

Lei Ma; Xiaowei Pan; Dongjing Hong; Huayi Fang; Peng Cui

doi:10.1039/d4cc00547c

A scandium metalloligand supported Ni(0) complex with a heterobimetallocycle: versatile reactivity with unsaturated bonds

Chem Commun (Camb). 2024 Apr 11;60(31):4222-4225. doi: 10.1039/d4cc00547c.

Authors

Lei Ma¹, Xiaowei Pan², Dongjing Hong¹, Huayi Fang², Peng Cui¹

Affiliations

¹ Key Laboratory of Functional Molecular Solids, Ministry of Education, Anhui Laboratory of Molecule-Based Materials, College of Chemistry and Materials Science, Anhui Normal University, S 189, Jiuhua Road, Wuhu, Anhui 241002, P. R. China. pcui@ahnu.edu.cn.
² School of Materials Science and Engineering, Nankai University, No. 38 Tongyan Road, Haihe Education Park, Tianjin 300350, P. R. China. hfang@nankai.edu.cn.

PMID: 38525969
DOI: 10.1039/d4cc00547c

Abstract

A N₂-bridged tetranuclear Sc(III)-Ni(0) complex featuring a Ni → Sc interaction and a 4-membered [Sc-N-C-Ni] ring was synthesized and characterized. Bimetallic reactivity was demonstrated via reactions with a series of unsaturated compounds containing NC, CN, CC, CO and NN bonds.