Preparation of lignin-based full-color carbon quantum dots and their multifunctionalization with waterborne polyurethanes

Abstract

Lignin is a popular material for energy transition and high-value utilization due to its low cost, non-toxicity, renewability, and widespread availability. However, its complex structure has hindered its application. Waterborne polyurethane (WPU) uses water as a dispersion medium, which is safer for humans and the environment but also leads to disadvantages such as poor mechanical properties and water resistance. In this study, we prepared multicolor photoluminescent carbon quantum dots (CQDs) in a wide range of wavelengths from lignin. We successfully prepared panchromatic CQDs by additive mixing. The redshift of the emission wavelength is attributed to the synergistic effect of the sp² conjugated structure and the surface functional groups. The full-color solid-state luminescence of the CQDs was successfully achieved, and most importantly, the application of full-color CQDs in light-emitting diodes was realized. Moreover, the embedding of the multicolor CQDs in WPU not only makes WPU luminescent but also improves the water resistance and mechanical properties of WPUs. The hydrogen-bonding interactions between the functional groups on the surface of the CQDs and the urethane were responsible for the high performance of the composite. We investigated the UV and strong blue light shielding abilities of WPU/yellow CQDs films, which resulted from the unique absorption peaks of yellow CQDs in the UV region and the strong blue light region. This work provides an efficient method for the high-value utilization of biomass materials and paves the way for the multifunctional application of WPU.

Keywords: Carbon quantum dots; Light emitting diode; Shielding performance; Solid state luminescence; Waterborne polyurethane.