Activated carbon adsorption is an effective method for removing perfluoroalkyl substances (PFAS) from water. However, the observation that higher concentrations of PFAS are observed after treatment than before (i.e., desorption) is an important, unsolved issue. In this study, to elucidate PFAS desorption and its relationship with PFAS properties, we conducted solvent extraction and long-term desorption experiments using granular activated carbon (GAC) that had been loaded with PFAS in two actual drinking water treatment plants. The amount of PFAS extracted from GAC depended on the depth in the GAC filter; longer-chain and hydrophobic PFAS were present in relatively higher amounts in the shallow part compared to the deep part of the GAC filter, whereas shorter-chain and hydrophilic PFAS were present in relatively higher amounts in the deep part compared to the shallow part. This pattern was probably due to a chromatographic effect by which hydrophilic PFAS adsorbed once, subsequently desorbed, and migrated from the shallow part of the GAC filter to the deeper part. The desorption potential of PFAS to water (i.e., the maximum amount of PFAS desorbed to water per unit mass of GAC) was estimated by conducting long-term bottle-point desorption tests and analyzing the relationship between the equilibrium water-phase concentration of PFAS in a bottle containing GAC and the amount of PFAS desorbed to water per unit GAC mass. The desorption ratio (ratio of desorption potential to loading) was the highest for PFAS for which the logarithm of the octanol/water distribution coefficient (Log DOW) ranged from -1 to 1. The implication was that most of those PFAS removed by GAC were likely to return to the water as the external water-phase concentrations dropped. The decrease of the desorption ratio to 20 % as Log DOW increased suggested irreversible adsorption due to hydrophobic affinity.
Keywords: Adsorption; Chain length; Equilibrium; Log D(OW); Solvent extractionm.
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