Selective production of phenolic monomer via catalytic depolymerization of lignin over cobalt-nickel-zirconium dioxide catalyst

Abstract

The utilization of lignin, an abundant and renewable bio-aromatic source, is of significant importance. In this study, lignin oxidation was examined at different temperatures with zirconium oxide (ZrO₂)-supported nickel (Ni), cobalt (Co) and bimetallic Ni-Co metal catalysts under different solvents and oxygen pressure. Non-catalytic oxidation reaction produced maximum bio-oil (35.3 wt%), while catalytic oxidation significantly increased the bio-oil yield. The bimetallic catalyst Ni-Co/ZrO₂ produced the highest bio-oil yield (67.4 wt%) compared to the monometallic catalyst Ni/ZrO₂ (59.3 wt%) and Co/ZrO₂ (54.0 wt%). The selectively higher percentage of vanillin, 2-methoxy phenol, acetovanillone, acetosyringone and vanillic acid compounds are found in the catalytic bio-oil. Moreover, it has been observed that the bimetallic Co-Ni/ZrO₂ produced a higher amount of vanillin (43.7% and 13.30 wt%) compound. These results demonstrate that the bimetallic Ni-Co/ZrO₂ catalyst promotes the selective cleavage of the ether β-O-4 bond in lignin, leading to a higher yield of phenolic monomer compounds.

Keywords: Bio-oil; Catalytic oxidation; Lignin; Phenolic monomers; Vanillin.