Synergistic mechanism and environmental behavior of tank-mix adjuvants to topramezone and atrazine

Environ Sci Pollut Res Int. 2024 Mar;31(13):20246-20257. doi: 10.1007/s11356-024-32389-9. Epub 2024 Feb 19.

Abstract

An effective way to reduce herbicide quantity is to use adjuvants in order to optimize the amount of herbicide and improve its control efficiency. In order to screen for efficient herbicide tank-mix adjuvants, improve the control of weeds in maize fields, reduce the amount of effective ingredients, and improve the adsorption and digestion behavior of herbicides in soil, this study evaluated the synergistic effects and soil behavior of four types of tank-mix adjuvants combined with herbicides. Different types of adjuvants can enhance herbicide production. Surface tension was significantly reduced by 13% after the pesticide solution was applied with AgroSpred™ Prime. The contact angle with the foliar surface was significantly reduced and solution wettability improved using Atp Lus 245-LQ-(TH). The permeability of topramezone and atrazine in leaves of Amaranthus retroflexus L. and Digitaria sanguinalis (L.) Scop. was increased by 22-96% after adding either tank-mix adjuvant. The solution drying time and maximum retention on leaves were not affected by the tank-mix adjuvants. Ethyl and methylated vegetable oils can reduce the adsorption of topramezone in the soil, thus reducing its half-life in soil. The tank-mix adjuvants had no significant effect on soil dissipation or adsorption of atrazine. AgroSpred™ Prime and Atp Lus 245-LQ-(TH) have the best synergistic effect on topramezone and atrazine in the control of A. retroflexus L. and D. sanguinalis (L.) Scop. in maize fields.

Keywords: Adsorption; Atrazine; Dissipation; Synergistic mechanism; Topramezone.

MeSH terms

  • Adenosine Triphosphate
  • Adjuvants, Immunologic
  • Atrazine*
  • Herbicides* / analysis
  • Pyrazoles*
  • Soil
  • Zea mays

Substances

  • Atrazine
  • topramezone
  • Herbicides
  • Adjuvants, Immunologic
  • Soil
  • Adenosine Triphosphate
  • Pyrazoles