Crystal structure and Hirshfeld surface analysis of dimethyl 4-hy-droxy-5,4'-dimethyl-2'-(toluene-4-sulfonyl-amino)-biphenyl-2,3-di-carboxyl-ate

Abstract

In the title compound, C₂₅H₂₅NO₇S, the mol-ecular conformation is stabilized by intra-molecular O-H⋯O and N-H⋯O hydrogen bonds, which form S(6) and S(8) ring motifs, respectively. The mol-ecules are bent at the S atom with a C-SO₂-NH-C torsion angle of -70.86 (11)°. In the crystal, mol-ecules are linked by C-H⋯O and N-H⋯O hydrogen bonds, forming mol-ecular layers parallel to the (100) plane. C-H⋯π inter-actions are observed between these layers.

Keywords: Hirshfeld surface analysis; [4 + 2] cyclo­addition; aryl­sulfonamides; crystal structure; furan; hydrogen bonds.