Characterization of Hydrothermally Decomposed and Synthesized CaCO3 Reinforcement from Dead Snail Shells

ACS Omega. 2024 Jan 4;9(2):2183-2191. doi: 10.1021/acsomega.3c05330. eCollection 2024 Jan 16.

Abstract

The development of new materials from marine resources presents a significant challenge due to the complexity of the associated materials and biology technologies. During this work, the snail shell, which naturally increases in thickness over time to protect the snail, has been identified as one of them. In this study, we investigated the use of powdered snail shells as a potential alternative to ceramics in the creation of customized composites. Our main objective is to explore the hydrothermal decomposition of the snail shell powder to remove undesirable components. To achieve this, we crushed and ground-washed dead snail shells and subjected them to hydrothermal decomposition using an autoclave and furnace at a temperature of 200, 220, 250, or 300 °C. We then analyzed the resulting samples using scanning electron microscope/energy-dispersive X-ray spectroscopy (SEM/EDS) and X-ray diffraction (XRD) techniques to determine changes in their composition and structure. Our findings demonstrate that all samples contained the elements Ca, C, and O, as confirmed by SEM/EDS results. XRD results show that hydrothermal decomposition at 250 °C led to good crystallization with maximum peak intensities observed at various diffraction angles. This indicates that the resulting material may have promising properties for use in composite materials. Overall, our study provides valuable insights into the use of snail shell powder as a potential material source for customized composites. Future studies could explore the optimization of the hydrothermal decomposition process and investigate the mechanical properties of the resulting materials to further develop this promising avenue of research.