Supramolecular Chemistry of Sumanene

Angew Chem Int Ed Engl. 2024 Apr 8;63(15):e202318437. doi: 10.1002/anie.202318437. Epub 2024 Feb 1.

Abstract

Sumanene is a buckybowl molecule that is continuously attracting the attention of the scientific community because of its unique geometrical and physicochemical properties. This Minireview systematically summarizes advances and considerations regarding the applied supramolecular chemistry of sumanene. This work highlights the major fields in which potential or real applications of sumanene molecule have been reported to date, such as the design of sumanene-containing functional supramolecular materials and architectures, sumanene-based drug-delivery systems, or sumanene-tethered ion-selective molecular receptors. An assessment of the current status in the applied supramolecular chemistry of sumanene is provided, together with an emphasis on the key advances being made. Discussion on those milestones that are still to be achieved within this emerging field is also provided.

Keywords: buckybowls; non-covalent interactions; sumanenes; supramolecular chemistry; synthesis.

Publication types

  • Review