N-doped carbon dots for the determination of Al3+ and Fe3+ using aggregation-induced emission

Abstract

New portable hydrogel sensors for Al³⁺ and Fe³⁺ detection were designed based on the aggregation-induced emission (AIE) and color change of N-doped carbon dots (N-CDs). N-CDs with yellow fluorescence were prepared by a one-pot hydrothermal method from 2,5-dihydroxyterephthalic acid and acrylamide. The fluorescence of N-CDs was enhanced by Al³⁺ about 20 times and quenched by Fe³⁺. It was interesting that although Fe³⁺ showed obvious quenching on the fluorescence of N-CDs it did not cause a noticeable change in the fluorescence of N-CDs + Al³⁺. The colorless solution of N-CDs appeared blue in the presence of Fe³⁺ without the influence of Al³⁺. Therefore, the turn-on fluorometry and colorimetry systems based on N-CDs were constructed for the simultaneous detection of Al³⁺ and Fe³⁺. Furthermore, the portable sensing of Al³⁺ and Fe³⁺ was realized with the assistance of hydrogel, filter paper, cellulose acetate, and cellulose nitrate film. The proposed approach was successfully applied to the detection of Al³⁺ and Fe³⁺ in food samples and cell imaging.

Keywords: Carbon dots; Cell imaging; Colorimetry; Fluorescence; Hydrogel sensor.