Schiff base derivates (3, 4 and 5) comprising pseudo cavity with different heteroatoms (O, N and S) were designed, synthesized and explored for their detection behaviour towards diverse metal ions. In UV and fluorescence studies, all three receptors exhibited sensitive response towards Cu2+ while 5 showed sensitivity for Hg2+ also. To explore the synthesized receptors for electrochemical behaviour, voltammetric studies were conducted where 3, 4 and 5 exhibited sensitive response towards Cu2+ with detection limits of 9.8 × 10-7 M, 9.0 × 10-7 M and 1.41 × 10-7 M, respectively. The receptor 5 also showed response towards Hg2+ with detection limit of 5.61 × 10-8 M. The formation of complexes, 3/4+Cu2+ and 5+Cu2+/Hg2+ was supported by large values of binding constant and associated negative free energy change. The binding mechanism of 3, 4 and 5 towards respective metal ions was confirmed using 1H-NMR and HR-MS studies. Further, to utilize the proposed sensors for on-site monitoring of analyte metal ions, carbon paste electrodes (CPEs) were constructed by incorporating 3, 4 and 5. All CPEs showed Nernstian response with lower detection limits and excellent selectivity and successfully utilized for the determination of Cu2+ and Hg2+ in groundwater samples.
Keywords: Carbon paste electrode; Dual sensor; Pseudo cavity; Schiff base; Voltammetric sensor.
Copyright © 2023 Elsevier B.V. All rights reserved.