The development of energetic materials is still facing challenges due to the inherent contradiction between energy and sensitivity. Two new nitrogen-rich energetic salts of 3,4,5-1H-trinitropyrazole (HTNP) were synthesized. They are fully characterized by X-ray diffraction, NMR, MS and IR spectroscopy. The DSC and BAM tests were carried out as well. These TNP salts show high thermostability and high positive heat of formation. Their detonation performances were calculated by the EXPLO5 program. Most noteworthy is that DATr salt exhibits superior sensitivity and detonation performance comparable to secondary explosive RDX, making it promising for use as a new-generation green energetic material.