Humidity sensing using Zn(1.6 - x)Na0.4CuxTiO4 spinel nanostructures

A M Mansour; Mohamed Morsy; Amany M El Nahrawy; Ali B Abou Hammad

doi:10.1038/s41598-023-50888-6

Humidity sensing using Zn_{(1.6 - x)}Na_0.4Cu_xTiO₄ spinel nanostructures

Sci Rep. 2024 Jan 4;14(1):562. doi: 10.1038/s41598-023-50888-6.

Authors

A M Mansour¹, Mohamed Morsy^{2

3}, Amany M El Nahrawy⁴, Ali B Abou Hammad⁵

Affiliations

¹ Solid State Physics Department, Physics Research Institute, National Research Centre (NRC), 33 El-Bohouth St., Dokki, Cairo, 12622, Egypt.
² Building Physics and Environment Institute, Housing and Building National Research Center (HBRC), Dokki, Giza, 12311, Egypt.
³ Nanotechnology Research Centre (NTRC), The British University in Egypt (BUE), Suez Desert Road, El-Sherouk City, Cairo, 11837, Egypt.
⁴ Solid State Physics Department, Physics Research Institute, National Research Centre (NRC), 33 El-Bohouth St., Dokki, Cairo, 12622, Egypt. amany_physics_1980@yahoo.com.
⁵ Solid State Physics Department, Physics Research Institute, National Research Centre (NRC), 33 El-Bohouth St., Dokki, Cairo, 12622, Egypt. abohmad2@yahoo.com.

Abstract

In this paper, we present a humidity sensing material based on nanostructured Zn_{(1.6 - x)}Na_0.4Cu_xTiO₄ spinel to enhance optical and sensitivity performance. Nano-porous of Zn _{(1.6 - x)} Na_0.4Cu_xTiO₄ spinel were synthesized using sol gel reactions and calcined at 700 °C. The nanostructures of Zn_{(1.6 - x)}Na_0.4Cu_xTiO₄ spinel underwent thorough characterization through multiple techniques. X-ray diffractometry (XRD) coupled with Rietveld refinement using FullProf software, transmission electron microscopy (TEM), Raman Spectroscopy, and optical analysis were employed to assess various aspects of the nanostructures. These techniques were utilized to determine the phase composition, particle size distribution, chemical bonding, and the tunable band gap of the nanostructures. The X-ray diffraction (XRD) analysis of Zn_{(1.6 - x)}Na_0.4Cu_xTiO₄ samples revealed well-defined and prominent peaks, indicating a highly crystalline cubic spinel structure. The lattice parameter was decreased from 8.4401 to 8.4212 Å with increasing Cu content from 0 to 1.2 mol%. UV-visible diffuse reflectance spectra were employed to investigate the optical characteristics of copper-doped Zn_1.6Na_0.4TiO₄. The applicability of Cu@NaZT spinel nanostructures in humidity sensors was evaluated at ambient conditions. The fabricated sensor was investigated in a wide span of humidity (11-97%). The examined sensor demonstrates a low hysteresis, excellent repeatability, fast response and recovery. The response and recovery times were estimated to be 20 s and 6 s respectively. The highest sensitivity was achieved at 200 Hz. The proposed sensor can be coupled easily with electronic devices as the humidity-impedance relationship is linear.