Conductive hydrogel which belongs to a type of soft materials has recently become promising candidate for flexible electronics application. However, it remains difficult for conductive hydrogel-based strain sensors to achieve the organic unity of large stretchability, high conductivity, self-healing, anti-freezing, anti-drying and transparency. Herein, a multifunctional conductive organohydrogel with all of the above superiorities is prepared by crosslinking polyacrylamide (PAM) with dialdehyde starch (DAS) in glycerol-water binary solvent. Attributing to the synergy of abundant hydrogen bonding and Schiff base interactions caused by introducing glycerol and dialdehyde starch, respectively, the organohydrogel achieved balanced mechanical and electrical properties. Besides, the addition of glycerol promoted the water-locking effects, making the organohydrogel retain the superior mechanical properties and conductivity even at extreme conditions. The resultant organohydrogel strain sensor exhibits desirable sensing performance with high sensitivity (GF = 6.07) over a wide strain range (0-697 %), enabling the accurate monitoring of subtle body motions even at -30 °C. On the basis, a hand gesture monitor system based on the organohydrogel sensors arrays is constructed using machine learning method, achieving a considerable sign language recognition rate of 100 %, and thus providing convenience for communications between the hearing or speaking-impaired and general person.
Keywords: Dialdehyde starch; Hydrogen bonding; Schiff base linkages.
Copyright © 2023. Published by Elsevier B.V.