Preparation and characterization of cellulose nanofibril/chitosan aerogels with high-adsorbability and sensitive indication for indoor free formaldehyde

Int J Biol Macromol. 2024 Feb;259(Pt 1):128891. doi: 10.1016/j.ijbiomac.2023.128891. Epub 2023 Dec 23.

Abstract

The toxic volatile organic compounds (VOCs), especially formaldehyde (FA), released from decoration materials pose a great threat to human health. In this study, formaldehyde adsorption performance of the specially formulated nanocellulose/chitosan aerogel (CNFCA) was investigated in simulated atmosphere. The physicochemical property of the composite aerogel was characterized, which had a large specific surface area (153.67 m2/g), a rough surface and an ultra-thin and porous structure. The composite aerogel showed excellent adsorption capacity for the formaldehyde, its theoretical maximum adsorption capacity was as high as 83.89 mg/g, and the adsorption process was more in accordance with the pseudo-second-order kinetics. The chromogenic reaction between the 4-amino-3-benzo-5-mercapto-1,2,4-triazolium (AHMT) and CNFCA was found that the color of the composite aerogel was depended on the free formaldehyde concentration. Based on this phenomenon, a colorimetric card was proposed and built to detection the formaldehyde in the atmosphere. Moreover, the adsorption mechanism research was found that the CNFCA with a multilayer structure belonged to physicochemical complex adsorption.

Keywords: Chitosan; Chromogenic reaction; Composite aerogel; Formaldehyde adsorption; Nanocellulose.

MeSH terms

  • Adsorption
  • Atmosphere
  • Cellulose
  • Chitosan*
  • Formaldehyde
  • Humans

Substances

  • Chitosan
  • Cellulose
  • Formaldehyde