This article presents the results of research on alkali-phenolic binders used in moulding sands. The results of the presented experiments are part of a search for the optimum conditions to implement the thermal regeneration of spent alkali-phenolic binder moulding sands. The cured binders were subjected to thermogravimetric analysis in aerobic and anaerobic atmospheres. On the basis of the resin decomposition curves, the integral polymer decomposition temperature was determined, and the required thermal regeneration temperature for the alkali-phenolic binder moulding sands that were used was determined according to a specific procedure. The spent moulding sand was subjected to roasting procedures at different temperatures in order to confirm the necessary regeneration temperatures. The effects of the procedures that were carried out were evaluated by means of weight losses and ignition losses, microscopic pictures were taken, and using scanning microscopy, an analysis of the chemical composition in the micro areas on the surfaces of the matrix grains was carried out using scanning microscopy. The indicators for the comparisons between the individual binders were also calculated from the mass losses. The research and analysis that were carried out made it possible to indicate the required temperature for the thermal regeneration of the spent alkali-phenolic binder moulding sand to reduce the involved energy expenditure. The factors that can determine the successful implementation of the process and the obtaining of the best possible grain matrix for reuse were also indicated.
Keywords: alkali-phenolic resin; process economics; spent moulding sand; thermal regeneration; thermogravimetric analysis.