The Microstructures, Mechanical Properties, and Deformation Mechanism of B2-Hardened NbTiAlZr-Based Refractory High-Entropy Alloys

Materials (Basel). 2023 Dec 11;16(24):7592. doi: 10.3390/ma16247592.

Abstract

The NbTiAlZrHfTaMoW refractory high-entropy alloy (RHEA) system with the structure of the B2 matrix (antiphase domains) and antiphase domain boundaries was firstly developed. We conducted the mechanical properties of the RHEAs at 298 K, 1023 K, 1123 K, and 1223 K, as well as typical deformation characteristics. The RHEAs with low density (7.41~7.51 g/cm3) have excellent compressive-specific yield strength (σYS/ρ) at 1023 K (~131 MPa·cm3/g) and 1123 K (~104.2 MPa·cm3/g), respectively, which are far superior to most typical RHEAs. And, they still keep appropriate plastic deformability at room temperature (ε > 0.35). The superior specific yield strengths are mainly attributed to the solid solution strengthening induced by the Zr element. The formation of the dislocation slip bands with [111](101_) and [111](112_) directions and their interaction provide considerable plastic deformation capability. Meanwhile, dynamic recrystallization and dislocation annihilation accelerate the continuous softening after yielding at 1123 K.

Keywords: B2 phase; deformation microstructure; refractory high-entropy alloys; specific yield strength; strain softening.