Handheld Crop Pest Sensor Using Binary Catalyst-Loaded Nano-SnO2 Particles for Oxidative Signal Amplification

ACS Sens. 2024 Jan 26;9(1):81-91. doi: 10.1021/acssensors.3c01669. Epub 2023 Dec 19.

Abstract

In agriculture, pest management is a major challenge. Crop releases volatiles in response to the pest; hence, sensing these volatile signals at a very early stage will ease pest management. Here, binary catalyst-loaded SnO2 nanoparticles of <5 nm were synthesized for the repeated capture and oxidation of the signature volatile and its products to amplify the chemoresistive signal to detect concentrations as low as ≈120 ppb. The sensitivity may be due to the presence of the elements in the Sn-Fe-Pt bond evidenced by extended X-ray absorption fine-structure spectroscopy (EXAFS) that captures and oxidize the volatile without escaping. This strong catalyst may oxidize nontarget volatiles and can cause false signals; hence, a molecular sieve filter has been coupled to ensure high selectivity for the detection ofTuta absolutainfestation in tomato. Finally, with the support of a mobile power bank, the optimized sensor has been assembled into a lightweight handheld device.

Keywords: SnO2; agriculture; gas sensor; pest detection; pest management; stress signature volatile.

MeSH terms

  • Agriculture
  • Nanoparticles*
  • Oxidation-Reduction
  • Oxidative Stress