Adsorption of Sb(III) and Pb(II) in wastewater by magnetic γ-Fe2O3-loaded sludge biochar: Performance and mechanisms

Abstract

Magnetically modified carbon-based adsorbent (BC@γ-Fe₂O₃) was prepared through facile route using activated sludge biomass and evaluated for the simultaneous removal of Sb(III) and Pb(II). BC@γ-Fe₂O₃ exhibited outstanding Sb(III) and Pb(II) adsorption capacity when 200 mg of adsorbent was employed at pH 5.0 for 240 min, with the removal efficiency higher than 90%. The experiments demonstrated the excellent reusability and the potent anti-interference properties of the prepared absorbent. Freundlich and pseudo-second-order kinetic were prior to describe the adsorption process. The adsorption of Sb(III) and Pb(II) onto BC@γ-Fe₂O₃ was spontaneous and endothermic. BC@γ-Fe₂O₃ with high specific surface area revealed the exceptional competence to absorb Sb(III) and Pb(II) through pore filling, electrostatic adsorption and complexation. The adsorption mechanisms of Sb(III) and Pb(II) showed similarities with slight disparities. The removal of Sb(III) involved the Fe-O-Sb bond and π-π bond, while the adsorption of Pb(II) was closely related to ion exchange. Moreover, Sb(III) was oxidized to Sb(V) in a minor part during adsorption. The Fe-O-Cl active sites on BC allowed for the binding of γ-Fe₂O₃, guaranteeing the abundant adsorption sites and stability. BC@γ-Fe₂O₃ provides an efficient and green insight into the simultaneous removal of complex heavy metals with promising application in wastewater treatment.

Keywords: Adsorption; Heavy metal; Magnetic microspheres; Sludge biochar modification.