Synthesis of Cs-symmetrical C60 tetra-adducts via reactions of C60Cl6 with CH-acids and enol silyl ester

Olga A Kraevaya; Alexander S Peregudov; Alexander F Shestakov; Pavel A Troshin

doi:10.1039/d3ob01868g

Synthesis of C_s-symmetrical C₆₀ tetra-adducts via reactions of C₆₀Cl₆ with CH-acids and enol silyl ester

Org Biomol Chem. 2024 Jan 3;22(2):374-379. doi: 10.1039/d3ob01868g.

Authors

Olga A Kraevaya¹, Alexander S Peregudov², Alexander F Shestakov^{1

3}, Pavel A Troshin^{1

4}

Affiliations

¹ Federal Research Center for Problems of Chemical Physics and Medicinal Chemistry of RAS, Semenov Prospect 1, Chernogolovka, 142432, Russia. okraevaya@inbox.ru.
² A.N. Nesmeyanov Institute of Organoelement compounds of RAS, Vavylova St. 28, B-334, Moscow, 119991, Russia.
³ Department of Fundamental Physics & Chemical Engineering, M.V. Lomonosov Moscow State University, Leninskie Gory 1/51, Moscow, 119991, Russia.
⁴ Zhengzhou Research Institute, Harbin Institute of Technology, Longyuan East 7th 26, Jinshui District, Zhengzhou, Henan Province, 450003, China.

PMID: 38086682
DOI: 10.1039/d3ob01868g

Abstract

Here we report the synthesis of novel fullerene derivatives with attached aliphatic residues based on the previously unknown reactions of chlorofullerene C₆₀Cl₆ with CH-acids and silyl enol ether.