Metal-organic frameworks (MOFs) are novel crystalline porous materials assembled from metal ions and organic ligands. The adaptability of their design and the fine-tuning of the pore structures make them stand out in porous materials. Furthermore, by integrating MOF guest functional materials with other hosts, the novel composites have synergistic benefits in numerous fields such as batteries, supercapacitors, catalysis, gas storage and separation, sensors, and drug delivery. This article starts by examining the structural relationship between the host and guest materials, providing a comprehensive overview of the research advancements in various types of MOF-functionalized composites reported to date. The review focuses specifically on four types of spatial structures, including MOFs being (1) embedded in nanopores, (2) immobilized on surface, (3) coated as shells and (4) assembled into hybrids. In addition, specific design ideas for these four MOF-based composites are presented. Some of them involve in situ synthesis method, solvothermal method, etc. The specific properties and applications of these materials are also mentioned. Finally, a brief summary of the advantages of these four types of MOF composites is given. Hopefully, this article will help researchers in the design of MOF composite structures.
Keywords: Functional materials; MOF composites; Structure; Synergistic effects; Synthesis strategies.
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