Optimum iron-pyrophosphate electronic coupling to improve electrochemical water splitting and charge storage

Rishabh Srivastava; Himanshu Chaudhary; Anuj Kumar; Felipe M de Souza; Sanjay R Mishra; Felio Perez; Ram K Gupta

doi:10.1186/s11671-023-03937-y

Optimum iron-pyrophosphate electronic coupling to improve electrochemical water splitting and charge storage

Discov Nano. 2023 Dec 4;18(1):148. doi: 10.1186/s11671-023-03937-y.

Authors

Rishabh Srivastava^{1

2}, Himanshu Chaudhary², Anuj Kumar³, Felipe M de Souza², Sanjay R Mishra⁴, Felio Perez⁵, Ram K Gupta^{6

7}

Affiliations

¹ Department of Physics, Pittsburg State University, Pittsburg, KS, 66762, USA.
² National Institute for Materials Advancement, Pittsburg State University, Pittsburg, KS, 66762, USA.
³ Nano-Technology Research Laboratory, Department of Chemistry, GLA University, Mathura, Uttar Pradesh, 281406, India. anuj.kumar@gla.ac.in.
⁴ Department of Physics and Materials Science, The University of Memphis, Memphis, TN, 38152, USA.
⁵ Integrated Microscopy Center, The University of Memphis, Memphis, TN, 38152, USA.
⁶ National Institute for Materials Advancement, Pittsburg State University, Pittsburg, KS, 66762, USA. ramguptamsu@gmail.com.
⁷ Department of Chemistry, Pittsburg State University, Pittsburg, KS, 66762, USA. ramguptamsu@gmail.com.

Abstract

Tuning the electronic properties of transition metals using pyrophosphate (P₂O₇) ligand moieties can be a promising approach to improving the electrochemical performance of water electrolyzers and supercapacitors, although such a material's configuration is rarely exposed. Herein, we grow NiP₂O₇, CoP₂O₇, and FeP₂O₇ nanoparticles on conductive Ni-foam using a hydrothermal procedure. The results indicated that, among all the prepared samples, FeP₂O₇ exhibited outstanding oxygen evolution reaction and hydrogen evolution reaction with the least overpotential of 220 and 241 mV to draw a current density of 10 mA/cm². Theoretical studies indicate that the optimal electronic coupling of the Fe site with pyrophosphate enhances the overall electronic properties of FeP₂O₇, thereby enhancing its electrochemical performance in water splitting. Further investigation of these materials found that NiP₂O₇ had the highest specific capacitance and remarkable cycle stability due to its high crystallinity as compared to FeP₂O₇, having a higher percentage composition of Ni on the Ni-foam, which allows more Ni to convert into its oxidation states and come back to its original oxidation state during supercapacitor testing. This work shows how to use pyrophosphate moieties to fabricate non-noble metal-based electrode materials to achieve good performance in electrocatalytic splitting water and supercapacitors.

Keywords: Electrocatalysts; Electrolyzer; HER; OER; Supercapacitor; Transition metal pyrophosphate; Water-splitting.