The design and development of novel efficient fluorescent chemical sensors for the selective detection of ions is currently of significant importance in supramolecular chemistry. Since zinc is a ubiquitous, indispensable and the second most abundant metal ion in the human body, developing chemosensors that can accurately discriminate between Zn2+ and Cd2+ ions has been a challenge due to their similar properties as they are in the same group of the periodic table. Therefore, a technique to trace and visualize free zinc ions is demanded. In this study, an innovative coumarin-based Schiff base (L) was synthesized and characterized by 1H NMR, 13C NMR and mass spectroscopy. A novel "Turn On" fluorescence chemosensor platform was developed for trace amounts of Zn2+ ions. The fluorescence Job's plot measurement was used to determine the complexation ratio between the probe and Zn2+ ion, which showed a maximum point indicating the formation of a ML2 adduct. Additionally, the geometrical parameters calculated using DFT and TD-DFT calculations were in close agreement with the experimentally observed values.
Keywords: Chemosensor; Coumarin; DFT; Fluorescence; Schiff base; Zinc.
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